The cells of the Purkinje fibers are noncontractile. They contain a few scanty, scattered, and more or less nonfunctional sarcomeres; they also contain a good deal of glycogen and a PAS stain will really make them stand out. This image shows the bundle of fibers that runs alongside the interventricular septum. There's such a bundle along both sides of the septum, one distributing to the right ventricle and one to the left ventricle. The Purkinje fibers are larger and less well stained than the ordinary contractile myocardium nearby.
Dog heart; H&E stain, paraffin section, 200x
*Yes, it's the same Purkinje who described the large integrator neurons of the brain. The term "Purkinje cell" can refer to either location, so "Purkinje fiber" is perhaps a better term in the context of the myocardial conduction fibers.